I use Windows 7 64bit and ran into the same problems as you, this is how I fixed it, and it's worked on multiple Windows 7 64bit machines.
Uninstall Diablo II completely, download the installers from blizzard. BEFORE you install Diablo II, right click on the install file and enable Windows XP compatibility and Run as Administrator. Then install Diablo II, do the same for Diablo II LoD BEFORE you install it and it fixes all color issues. You can freely alt+tab in full screen mode with no issues.
Thats cuz that pala prob had 20k forum gold. It's not unreasonable for there to be rune drops within the first day of the ladder, just takes the guy with the most amount of resources to be able to buy those runes early on.
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Uninstall Diablo II completely, download the installers from blizzard. BEFORE you install Diablo II, right click on the install file and enable Windows XP compatibility and Run as Administrator. Then install Diablo II, do the same for Diablo II LoD BEFORE you install it and it fixes all color issues. You can freely alt+tab in full screen mode with no issues.
Hopefully this works for you =D